When a user right-clicks on a matrix in the Desktop Client, the matrix is built by retrieving the mapping properties for the matrix row. These are on the interfaces implied by ISPFDistributionMapRow. Each property on the matrix row interface is mapped to a property or relationship on the object in the workflow.
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Create the matrix.
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Assign recipients to the matrix. See Matrix management.
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Relate the matrix to the workflow step. See Assign recipients to a workflow step.